The battery systems to drive the HV switchgear, power the telecoms, relay protection, emergency lighting etc. in practically all the existing substations are of lead-acid chemistry. These batteries are simple and reliable.
However they take too much of the precious floor space, they might be too heavy to be installed on higher levels if there are more than one floor in the substation, and some of them require special battery rooms equipped with the emergency showers, forced ventilation, soda ash bags etc. which is all costly at the end of the day.